|
|
3,5-dihydroxyphenylacetyl-CoA + O2 <=> (3,5-dihydroxyphenyl)(oxo)acetate + CoA + H+
|
1.13.11.80
(3,5-dihydroxyphenyl)acetyl-CoA 1,2-dioxygenase
|
–
|
| |
BRENDA:
BR51204
KEGG:
R06624
MetaCyc:
RXN-16269
|
|
|
|
dTDP-glucose <=> H2O + dTDP-4-dehydro-6-deoxy-D-glucose
|
4.2.1.46
dTDP-glucose 4,6-dehydratase
4.2.1.76
UDP-glucose 4,6-dehydratase
|
–
–
|
| |
BRENDA:
BR425
KEGG:
R06513
MetaCyc:
DTDPGLUCDEHYDRAT-RXN
SABIO-RK:
2648;
8948
|
|
|
|
(S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + O2 <=> 4-hydroxyphenylglyoxylate + H2O2
|
1.1.3.46
4-hydroxymandelate oxidase
|
–
|
| |
BRENDA:
BR50849
KEGG:
R06633
MetaCyc:
RXN-15300
|
|
|
|
malonyl-CoA + H+ <=> 3,5-dihydroxyphenylacetyl-CoA + CoA + CO2 + H2O
|
2.3.1.246
3,5-dihydroxyphenylacetyl-CoA synthase
|
–
|
| |
BRENDA:
BR51223
KEGG:
R06625
MetaCyc:
RXN-16276
|
|
|
|
(S)-3,5-dihydroxyphenylglycine + 2-oxoglutarate <=> (3,5-dihydroxyphenyl)(oxo)acetate + L-glutamate
|
2.6.1.103
(S)-3,5-dihydroxyphenylglycine transaminase
|
–
|
| |
BRENDA:
BR50675
KEGG:
R06634
MetaCyc:
RXN-14845
|
|
|
|
4-hydroxyphenylpyruvate + O2 <=> (S)-2-Hydroxy-2-(4-hydroxyphenyl)acetate + CO2
|
1.13.11.46
4-hydroxymandelate synthase
|
–
|
| |
BRENDA:
BR29129
KEGG:
R06632
|
|
|
|
dTDP-3-amino-2,3,6-trideoxy-C-methyl-D-erythro-hexopyranos-4-ulose <=> dTDP-L-4-oxovancosamine
|
5.1.3
|
–
|
| |
KEGG:
R06628
MetaCyc:
RXN-15226
|
|
|
|
dTDP-4-dehydro-6-deoxy-D-glucose <=> dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose + H2O
|
4.2.1.159
dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase
|
–
|
| |
BRENDA:
BR51535
KEGG:
R05518
MetaCyc:
RXN-16567
|
|
|
|
4-hydroxyphenylglyoxylate + L-tyrosine <=> L-4-hydroxyphenylglycine + 4-hydroxyphenylpyruvate
|
2.6.1.103
(S)-3,5-dihydroxyphenylglycine transaminase
2.6.1.B17
|
–
–
|
| |
BRENDA:
BR52009
KEGG:
R06626
|
|
|
|
dTDP-beta-L-4-epi-vancosamine + NADP+ <=> dTDP-L-4-oxovancosamine + NADPH + H+
|
1.1.1
|
–
|
| |
KEGG:
R06629
MetaCyc:
RXN-15225
|
|
|
|
S-adenosyl-L-methionine + dTDP-3-amino-2,3,6-trideoxy-4-keto-D-glucose <=> dTDP-3-amino-2,3,6-trideoxy-C-methyl-D-erythro-hexopyranos-4-ulose + S-adenosyl-L-homocysteine + H+
|
2.1.1
|
–
|
| |
KEGG:
R06627
MetaCyc:
RXN-15227
|
|
|
|
dTDP-3-amino-2,3,6-trideoxy-4-keto-D-glucose + 2-oxoglutarate <=> dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose + L-glutamate
|
2.6.1
|
–
|
| |
KEGG:
R06631
MetaCyc:
RXN-15233
|
|
|
|
dTDP-L-4-oxovancosamine <=> dTDP-beta-L-vancosamine
|
not assigned
|
–
|
| |
KEGG:
R06630
|
|
